{"id":563,"date":"2026-03-02T17:04:33","date_gmt":"2026-03-02T16:04:33","guid":{"rendered":"https:\/\/jwhaverkort.weblog.tudelft.nl\/?p=563"},"modified":"2026-03-03T13:56:03","modified_gmt":"2026-03-03T12:56:03","slug":"pulsed-water-electrolysis-usually-worse-compared-to-dc","status":"publish","type":"post","link":"https:\/\/jwhaverkort.weblog.tudelft.nl\/?p=563","title":{"rendered":"Pulsed Water Electrolysis usually worse compared to DC"},"content":{"rendered":"\n<p>An often mentioned simple way to improve water electrolysis is to modulate the current, for example, by rapidly switching it on and off periodically. Many papers report improvements without a fair comparison with the non-modulated (DC) case. In such a comparison, the same amount of hydrogen is produced per unit time, so that the average current over time is equal.<\/p>\n\n\n\n<p>Unfortunately, doing exactly this, we found no positive effect of modulating the current in the 0.01-1000 kHz range.<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"584\" src=\"https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-1024x584.png\" alt=\"\" class=\"wp-image-564\" srcset=\"https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-1024x584.png 1024w, https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-300x171.png 300w, https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-768x438.png 768w, https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-1536x876.png 1536w, https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-500x285.png 500w, https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image.png 1553w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p>This is easy to understand, because energy losses usually increase more than linearly with current density: to obtain the same average current density, the lower energy losses at lower-than-average current are more than offset by the higher energy losses during periods of higher-than-average current.<\/p>\n\n\n\n<p>There are a few noteworthy exceptions: for example, at low currents, the stack losses can decrease with increasing current density due to shunt currents. Also, by modulating at the time scale of gas build-up, a small advantage may be obtained. Finally, there may be a regime at extremely high frequencies at which the catalysis will be influenced. However, in general, claims of improvement should be considered with healthy scepticism.<\/p>\n\n\n\n<p>For a cell voltage <em>V<sub>0<\/sub>+ARj<\/em>, the larger the difference between the high current (<em>j<\/em><sub>high<\/sub>) and low current (<em>j<\/em><sub>high<\/sub>), and the larger the fraction of the time <em>D<\/em> or <em>1-D<\/em> that the current is high or low, the higher the specific energy consumption (SEC) compared to DC (<em>j<\/em><sub>av<\/sub>) :<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"256\" height=\"54\" src=\"https:\/\/jwhaverkort.weblog.tudelft.nl\/files\/2026\/03\/image-1.png\" alt=\"\" class=\"wp-image-565\" \/><\/figure>\n\n\n\n<p>This prediction was nicely validated by in-house experiments with an AEM cell.<\/p>\n\n\n\n<p><a href=\"https:\/\/doi.org\/10.1016\/j.ijhydene.2026.154195\">Anamika Ghosh, J.W. Haverkort, Modulating the current in water electrolysis does not increase energy efficiency compared to a constant equal average current, International Journal of Hydrogen Energy, Volume 221, 2026, 154195<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>An often mentioned simple way to improve water electrolysis is to modulate the current, for example, by rapidly switching it on and off periodically. Many papers report improvements without a fair comparison with the non-modulated (DC) case. In such a &hellip; <a href=\"https:\/\/jwhaverkort.weblog.tudelft.nl\/?p=563\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":6225,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/posts\/563"}],"collection":[{"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/users\/6225"}],"replies":[{"embeddable":true,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=563"}],"version-history":[{"count":4,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/posts\/563\/revisions"}],"predecessor-version":[{"id":571,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=\/wp\/v2\/posts\/563\/revisions\/571"}],"wp:attachment":[{"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=563"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=563"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/jwhaverkort.weblog.tudelft.nl\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=563"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}